![Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)?[(S)-dm-segphos?],二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II)](https://static.jkchemical.com/Structure/807/807539.png)
二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II)
Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)?[(S)-dm-segphos?]
分子式: C??H??O?P?Ru
分子量: 941.95
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior
enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-ß-ketoesters. See 15-0066
2. Ruthenium catalyzed enantioselective synthesis of ß amino acids by hydrogenation.
References:
1. US. Pat 7626034
