![Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)₂[(S)-dm-segphos®],二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II)](https://static.jkchemical.com/Structure/807/807539.png)
二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II)
Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)₂[(S)-dm-segphos®]
分子式: C₅₀H₅₀O₈P₂Ru
分子量: 941.95
纯度: null
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基本信息
中文名称二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II) | 英文名称Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)₂[(S)-dm-segphos®] |
产品编号44-0176 | 分子式C₅₀H₅₀O₈P₂Ru |
CAS号944450-50-4 | 分子量941.95 |
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior
enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of a-substituted-ß-ketoesters. See 15-0066
2. Ruthenium catalyzed enantioselective synthesis of ß amino acids by hydrogenation.
References:
1. US. Pat 7626034
