(+)-1,2-双((2R,5R)-2,5-二乙磷酰亚基)苯 , 98+%
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
分子式: (C₆H₁₂)PCH₂CH₂P(C₆H₁₂)
分子量: 258.33
纯度: 98+%
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![Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)₂[(S)-dm-segphos®],二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II)](https://static.jkchemical.com/Structure/807/807539.png)
基本信息
中文名称(+)-1,2-双((2R,5R)-2,5-二乙磷酰亚基)苯 | 英文名称(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE |
产品编号15-0104 | 分子式(C₆H₁₂)PCH₂CH₂P(C₆H₁₂) |
CAS号129648-07-3 | 分子量258.33 |
产品纯度98+% | |
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Ligand for Cu- catalyzed enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines to prepare a chiral amines .
2.Used in the Pd-catalyzed allylation of aliphatic alcohols.
3.Ligand for Rh-catalyzed enantioselective carbonyl hydroacylation.
4.Ligand for cobalt-catalyzed asymmetric alkene hydroge nation.
References:
1.J. Am. Chem. Soc., 2003, 125, 1692.
2.J. Org. Chem., 2003, 68, 8092.
3.J. Am. Chem. Soc.. 2008, 130, 2916.
4.Science, 2013, 342, 1076.
