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基本信息
中文名称氯代-1，5-环戊二烯铱二聚物 | 英文名称Chloro-1,5-cyclooctadiene iridium(I) dimer, 99% |
产品编号77-0400 | 分子式[IrCl(C₈H₁₂)] |
CAS号12112-67-3 | 分子量671.71 |
产品纯度99% | |
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
2.Precursor to catalyst for enantioselective reduction of imines.
3.Precursor to catalyst for allylic alkylation.
4.Precursor to catalyst for allylic amination and etherification.
5.Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
6.Ir-catalyzed addition of acid chlorides to terminal alkynes.
7.Intramolecular hyd roamination of unactivated alkenes with secondary alkyI- and arylamines.
8.Enantioselective 2+ 2 cycloaddition.
9.Silyl-directed, Ir-catalyzed ortho-b orylation of arenes.
10.Ir-catalyzed cros s-coupling of styrene derivatives with allylic carbonates .
11.Transfer hydrogenative C-C coupling
References:
1.Angew. Chem. Int. Ed., 1998, 37, 2897.
2.J. Am. Chem. Soc., 1999, 121, 6421.
3.J. Am. Chem. Soc., 1998, 120, 8647.
4.J. Am. Chem. Soc, 2003, 125, 14272.
5.J. Am. Chem. Soc., 2002, 124, 12680.
6.J. Am. Chem. Soc, 2009, 131, 6668.
7.J. Am. Chem. Soc., 2010, 132, 413.
8.Org. L ett., 2010, 12, 304.
9.J. Am. Chem. Soc, 2008, 130, 7534.
10.J. Am. Chem. Soc., 2009, 131, 8346.
11.（a）J. Am. Chem. Soc., 2008, 130, 6340. (b) Angew. Chem. Int. Ed., 2009, 48, 6313.
