![(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh,1,2-双[(2S,5S)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I) , min. 98%](https://static.jkchemical.com/Structure/807/807751.png)
1,2-双[(2S,5S)-2,5-二苯基膦]乙烷(1,5-环辛二烯)四氟硼酸铑(I) , min. 98%
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-Ph-BPE-Rh
分子式: [Rh(C?H??)(C??H??P?)]?BF
分子量: 804.49
纯度: min. 98%
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Technical Notes:
1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
References:
1. Org. Lett., 2003, 5, 1273.
2. Tetrahedron Lett, 2004, 45, 9277.
3. Angew. Chem. Int. Ed., 2005, 44, 5834.
