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基本信息
中文名称(R)-(-)-1-[(S)-2-二苯基磷]二茂铁乙基二环己基磷 | 英文名称(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, min. 97% (R)-(S)-JOSIPHOS |
产品编号26-1210 | 分子式C₃₆H₄₄FeP₂·CH₃CH₂OH |
CAS号155806-35-2 | 分子量594.59 (640.66) |
产品纯度min. 97% | 存储温度(℃)Store at 2-8℃ |
安全信息
存储条件Store at 2-8℃ |
化学和物理性质
产品描述
Technical Notes:
1.Ligand for Palladium-catalyzed amination of aryl halides .
2.Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene .
3.L igand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with orga noboronic acids .
4. L igand for Copper catalyzed asymmetric 1 ,4 -hyd rosilylations of a,ß-unsaturated esters .
5. L igand for Ruthenium-catalyzed asymmetric hyd rogenation of N-sulfonated-a-dehydroamino acids .
6.L igand for Rhodium-catalyzed a symmetric hydrogenation of enamines
7.Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates.
8.L igand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides .
9. L igand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a c-c bond.
10.L igand for Rh-catalyzed Asymmetric Hydrogenation of enamine substrates.