![(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX,二氢二苯磷苯基-4-异丙恶唑 , 98%](https://static.jkchemical.com/Structure/177/177081.png)
二氢二苯磷苯基-4-异丙恶唑 , 98%
(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
分子式: C₂₄H₂₄NOP
分子量: 373.44
纯度: 98%
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基本信息
中文名称二氢二苯磷苯基-4-异丙恶唑 | 英文名称(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX |
产品编号15-1822 | 分子式C₂₄H₂₄NOP |
CAS号148461-14-7 | 分子量373.44 |
产品纯度98% | |
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Chiral ligand used in the asymmetric reduction of highly substituted olefins
2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to
the fact that the catalytic system does not promote double bond isomerization.
2.Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole .
3.Decarboxylative allylic alkylation.
References:
1. Angew. Chem. Int. Ed., 1998, 37, 2897.
2. Angew. Chem. Int. ., 1996, 35, 200.
3. Acc. Chem. Res. 2000, 33, 336.
4. Eur. J. Org. Chem.. 2011, 31, 6288.
5. Org. Lett., 2014, 16, 118.
