![(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,S)-N-PINAP,（S)-(-)-4 - [2 - （二苯基膦）- 1 -萘]- N-[（R）- 1-苯乙基] -1 - 二氮杂萘胺 , min. 97%](https://static.jkchemical.com/Structure/627/627051.png)
（S)-(-)-4 - [2 - （二苯基膦）- 1 -萘]- N-[（R）- 1-苯乙基] -1 - 二氮杂萘胺 , min. 97%
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,S)-N-PINAP
分子式: C₃₈H₃₀N₃P
分子量: 559.64
纯度: min. 97%
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Technical Notes:
1.. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
References:
1.Angew. Chem. Int. Ed., 2004, 43, 5971.
2.Org. L ett 2006, 8, 2437
3.J. Am. Chem. Soc., 2005, 127, 9682.
