![(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin,(3aS,8aS)-(+)-4,4,8,8四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-E]二噁磷杂庚英](https://static.jkchemical.com/Structure/152/1523828.png)
(3aS,8aS)-(+)-4,4,8,8四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-E]二噁磷杂庚英
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
分子式: C₄₅H₄₉O₄P
分子量: 684.84
纯度: null
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基本信息
中文名称(3aS,8aS)-(+)-4,4,8,8四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧杂环戊烯并[4,5-E]二噁磷杂庚英 | 英文名称(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin |
产品编号15-1512 | 分子式C₄₅H₄₉O₄P |
CAS号1169835-86-2 | 分子量684.84 |
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Chiral ligand used in the nickel-catalyzed, enantios elective, conjugate allylation of activated enones.
2.Chiral ligand used in the platinum-catalyzed, asymmetric, 1 ,4-dihydroxylation of 1,3-dienes via catalytic enantios electivediboration.
3.Chiral ligand used in the platinum-catalyzed, asymmetric addition of Bz(pin)z to N-silyl imines for the synthesis of a- aminoboronates.
4. Asymmetric 1,4 dihydroxylation of 1,3 dienes by catalytic enantios elective diboration.
References: 1. J. Am. Chem. Soc., 2008, 130, 4978. 2.J. Am. Chem. Soc.,2009, 131, 9134. 3.J. Am. Chem. Soc., 2013, 135, 9252 . 4.Chem. Sci., 2015, 6, 51 64.
