R-(+)-6,6'-双(二苯基磷)-2,2',3,3'-四氢-5,5'-二-1,4-苯并二辛烷 , min. 94%
R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 94% (R)-SYNPHOS
分子式: C??H??O?P
分子量: 638.63
纯度: min. 94%
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1. A chiral diphosphine ligand used in the highly- enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
2. A ligand used for the dynamic kinetic resolution of o,ß- unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
3. Used in the intramolecular Heck reaction for the synthesis of diterpenoids .
4. Used in asymmetric Pauson-Khand reaction.
5.Used in asymmetric iminonitroso Diels-Alder reaction.
6.Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines .
7.Ligand for asymmetric hydroalkynylation of norbornadienes