![(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox,(+)-2,6-双[(4S)-4-(异丙基)-2-恶唑啉-2-基]吡啶 , 98+%](https://static.jkchemical.com/Structure/358/358083.png)
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基本信息
中文名称(+)-2,6-双[(4S)-4-(异丙基)-2-恶唑啉-2-基]吡啶 | 英文名称(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox |
产品编号07-0307 | 分子式C₁₇H₂₃N₃O |
CAS号118949-61-4 | 分子量301.38 |
产品纯度98+% | |
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
2.Ligand for cross-coupling reactions of iodoalkanes with alkyI zinc halides.
3.L igand for asymmetric 1 , 4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes .
4.L igand for asymmetric allylation of alde hydes with b-carbonyl allylstannanes.
5.L igand used in the enantioselective Negishi reaction of racemic secondary benzylic halides. L igand for osmium catalyzed enantioselective transfer hydrogenation.
References:
1. J. Am. Chem. Soc., 2004, 126, 9928.
2.Angew. Chem. Int. Ed., 2007, 46, 87 90.
3.Angew. Chem. Int. Ed., 2009, 48, 91 1 7.
4.J. Organomet. Chem, 2010, 695, 128.
5. J. Am. Chem. Soc. 2005, 127, 10482. Inorg. Chem.2013, 52, 6193.
