[S(R)]-N-[(1S)-1- [2-(9-蒽基)苯基] -2-(二苯基膦基)乙基] -2-甲基-2-丙烷亚磺酰胺,95% , 95%
[S(R)]-N-[(1S)-1-[2-(9-Anthracenyl)phenyl]-2-(diphenylphosphino)ethyl]-2-methyl-2-propanesulfinamide, 95%
分子式: C??H??NOPS
分子量: 585.7
纯度: 95%
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Technical Notes:
1.Organocatalyst used in enantioselective intermolecular cross Rauhut-Currier reactions of activated alkenes with acrolein.
2.Used in phosphine catalyzed asymmetric umpolung addition of trifluoromethyl ketimines to Morita- Baylis- Hillman carbonates.
3.Used in the enantioselective phosphine- catalyzed allylic alkylations of mix-indene with MBH carbonates.
4.Used in phos phine-catalyzed asymmetric synthesis of a-quaternary amine via um polung y-addition of
ketimines to allenoates.
5.Ligand for the direct Pd-catalyzed cross-coupling reaction of easily acce ssible secondary phosphine oxides and aryl bromides, which provides rapid access to P-chiral phosphine oxides.