二-μ-碘代二(乙二胺)硝酸二铂(II) , 99%
Di-μ-iodobis(ethylenediamine)diplatinum(II) nitrate, 99% PIP
分子式: [Pt?I?(H?NCH?CH?NH?)?](NO?)
分子量: 888.20
纯度: 99%
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基本信息
安全信息
化学和物理性质
产品描述
Technical Note:
1. Widely used in complex multi-step organic syntheses. This mild hydration catalyst converts hindered and acid/base sensitive nitriles to amides. The amide is released from the metal coordination sphere preventing further hydrolysis to acid. Typically . turnover frequency (TOF) ranges from 16 to 380 h-1 depending on steric factors. For optimal results avoid the presence of coordinating anions especially cyanide and halide.
References:
1.J.Org.Chem.2004, 69, 2327.
2.Org. Lett, 2006. 8. 2643
3.J. Org Chem.. 2009. 74. 5405.
4.Tetrahedron Lett.，2010，51，6422
5. Appl. Sci. 2015, 5, 380. (catalyst review article)
