二氯[(S) - ( - )-2,2' - 双(二苯基膦基)-1,1' - 联萘]合钯(Ⅱ) , min. 98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
分子式: PdCl₂(C₄₄H₃₂P₂)
分子量: 800.00
纯度: min. 98%
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Technical Notes:
1. Catalyst precursor, with AgBF4. for the enantioselective addition of silyl ethers, to imines to produce ß- amino ketones, and t aldehydes to produce 3-hydroxy-1-propanone aldol addition products
2. Catalyst precursor, with AgSbFe, for the asymmetric carbonylene reaction,
3.Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals .
References:
1. J. Am. Chem. Soc.. 1999, 12, 15450.
2.Tetrahedron L ett. 2006, 47. 3956.
3.Organometallics, 2007. 26, 5961.
4.Tetrahedron, Asymm., 2004.15, 3885.
5.Tetrahedron Lett. 1998, 39, 6253.
6. J. Org. Chem., 1999 648660.