Tetrakis[(S)-(+)-[(1S)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II) Rh2(S-BTPCP)4,四[(S)-(+)-[(1S)-1-(4-溴苯基)-2,2-二苯基环丙烷羧酸酯]二铑(II)
四[(S)-(+)-[(1S)-1-(4-溴苯基)-2,2-二苯基环丙烷羧酸酯]二铑(II)
Tetrakis[(S)-(+)-[(1S)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II) Rh2(S-BTPCP)4
品牌: Strem
产品编号: 45-2081
分子式: C88H64Br4O8Rh2
分子量: 1774.87
纯度: null
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基本信息

安全信息

化学和物理性质

产品描述

Technical Notes:

1.Chiral catalyst used for the enantios elective formation of cyclopropanes from the reaction of aryls with styryl diazoacetates

2. Chiral catalyst used for the asymmetric synthesis of bicyclo1.1.obutane rings via the rhodium-catalyzed d ecomposition of 2-diazo-5- arylpent-4-enoates.

3. Rhodium-Catalyzed 4+3 Cycloaddition between Vinyldiazoacetates and Dienes

References :

1. J. Am. Chem. Soc.. 2011, 133, 19198.

2.Org. Lett. 2013, 15, 310.

3.Angew. Chem. Int. Ed.. 2014, 53, 13083.

参考文献