(R)-(+)-2,2',6,6'-四甲氧基-4,4'-二(二苯基膦基)-3,3'-联吡啶(1,5-环辛二烯)铑(I)四氟硼酸,min.97% , min. 97%
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
分子式: [C??H??N?O?P?Rh]?BF
分子量: 942.53
纯度: min. 97%
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Chiral ligand for enantios elective rhodium-catalyzed 2+2+2 carbocyclization reactions .
2.Chiral ligand for the asymmetric hydrogenation of ß-keto esters .
3.Highly enantios elective hydrogenation of ß- alkyl-substituted (E)-ß-(acylamino)- acrylates
References : 1. J. Am. Chem. Soc. 2005, 127, 12466. 2.J.Org.Chem., 2003, 68, 2490.
