(-)-1,2-双((2s,5s)-2,5-二异丙基膦酸)苯(1,5-环辛二烯)铑(I)四氟硼酸盐 , 98%
(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (S,S)-i-Pr-DUPHOS-Rh
分子式: [Rh(C?H??)(C??H??P?)]?BF
分子量: 716.47
纯度: 98%
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基本信息
安全信息
化学和物理性质
产品描述
Technical Note:
1. The NOYORI catalysts are a ruthenium-based systom containing a phosphine and 1.2-diamine ligand. The catalysts are usod in the highly-officiont, enantio and diasteroosoloctivo hydrogenation of simplo kotonos, usually undor the mild conditions of room tomporature and 1-10 atm of hydrogon prossuro.
References:
1.J.Org. Chem., 1996. 61.4872.
2. Angew. Chem. Int. Ed.. 2001. 40. 40 (review article).
3.J. Am. Chem. Soc.. 1998, 120, 13529
4Angew. Chem. Int. Ed. 1999, 38, 495.
