(2R,3R)-(-)-2,3-双(二苯基膦基)双环[2.2.1]庚-5-烯(1,5-环辛二烯)铑(I)四氟硼酸盐 , min. 97%
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
分子式: [Rh(C?H??)(C??H??P?)]?BF
分子量: 760.39
纯度: min. 97%
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1. L igand used in the enantioselective rhodium catalyzed hydrogenation of a dehydroaminoesters and enamides.
2. L igand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1 ,3-oxazolidines.
References:
1. Angew. Chem., 1979, 91, 655.
2. J. Am. Chem. Soc.. 2003, 125, 7198.
3. Adv. Synth. Catal. 2003, 345, 239.