![Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][(phenylthio)methylene]ruthenium(II) dichloride,三环己基膦[1,3-双(2,4,6-三甲基苯基)-4,5-二氢咪唑-2-亚基][(苯硫基)亚甲基]钌(II)二氯](https://static.jkchemical.com/Structure/109/1094085.png)
三环己基膦[1,3-双(2,4,6-三甲基苯基)-4,5-二氢咪唑-2-亚基][(苯硫基)亚甲基]钌(II)二氯
Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][(phenylthio)methylene]ruthenium(II) dichloride
分子式: RuCl?[C??H??N?][C?H?S][P(C?H??)?]
分子量: 881.04
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Metathesis catalyst, stable in air and can be used in aqueous media .
2.Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins .
3.Catalyst concentration 2-3 times lower than com parable phenyI and vinyI substituted rutheniumcarbenes.
4.Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.
5.Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.
References:
1.J. Org· Chem.. 2000, 606, 65.
2.“Ring Opening Metathesis Polymerization of Related Chemistry", NATO Science Series II, 2002, 23. 3. 3.Organometallics, 2003, 22, 586.
