![Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH₂Me₂][{RuCl((R)-H₈-binap)}₂(μ-Cl)₃],二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5'，6,6'，7,7'，8,8'-八氢-1,1'-联萘]二钌(Ⅱ)](https://static.jkchemical.com/Structure/792/792331.png)
二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5'，6,6'，7,7'，8,8'-八氢-1,1'-联萘]二钌(Ⅱ)
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH₂Me₂][{RuCl((R)-H₈-binap)}₂(μ-Cl)₃]
分子式: (CH₃)₂NH₂⁺[C₈₈H₈₀Cl₅P₄Ru₂]
分子量: 1685.96
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes :
1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturate carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug lbuprofen.
References:
1. J. Org. Chem.. 1996. 61. 5510
2. Topics Organometal. Chem. 2004, 6. 63 (review).
