![Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)?[(S)-dtbm-segphos?],二乙酸基{（S）-（+）-5,5'-双[二（3,5-二-叔-丁基-4-甲氧基苯基）膦基]-4,4'-双-1,3-苯并间二氧杂环戊烯}钌（II）](https://static.jkchemical.com/Structure/100/1001100.png)
二乙酸基{（S）-（+）-5,5'-双[二（3,5-二-叔-丁基-4-甲氧基苯基）膦基]-4,4'-双-1,3-苯并间二氧杂环戊烯}钌（II）
Diacetato{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)?[(S)-dtbm-segphos?]
分子式: C??H???O??P?Ru
分子量: 1398.69
纯度: null
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![二乙酸基{(S)-(+)-5,5'-双[二(3,5-二-叔丁基-4-甲氧基苯基)膦基]-4,4'-双-1,3-苯并间二氧杂环戊烯}钌(II),二乙酸基{(S)-(+)-5,5'-双[二(3,5-二-叔丁基-4-甲氧基苯基)膦基]-4,4'-双-1,4-苯并间二氧杂环戊烯}钌(II)](https://static.jkchemical.com/Structure/922/9222194.png)
基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-S EGPHOS ligand, as the ruthenium complex, gives superior
ena ntioselectivity and dias te re oselectivity in the asymmetric hydrogenation of a-subs tituted- ß-ke toesters. See 1 5-0066
2.Ruthenium catalyzed enantioselective synthesis of ß amino acids by hyd rogenation
3.Ruthenium catalyzed asymmetric hydrogenation of 3 quinuclidinone. See 44-0098 for Ru catalyst.
References:
1. WIPO Pat. WO20050284 19.
2. u.S. Pat. App.2006047122.
