![Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)?[(S)-H?-binap],(S)-钌(醋酸)2(H8-BINAP）](https://static.jkchemical.com/Structure/791/791976.png)
(S)-钌(醋酸)2(H8-BINAP）
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)?[(S)-H?-binap]
分子式: C??H??O?P?Ru
分子量: 849.89
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)
2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
References:
1. J. Org. Chem., 1996, 61, 5510.
2. Topics Organometal. Chem. 2004, 6, 63 (review).
