五甲基环戊二烯基双(三苯基膦)氯化钌(II) , 99%
Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%
分子式: RuCl(C??H??)[P(C?H?)?]
分子量: 796.32
纯度: 99%
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产品描述
Technical Notes:
1. Effective catalyst for the regioselective cycloaddition of organic azides and terminal alkynes, producing 1 ,5-substituted triazoles. This "click" reaction complements the related copper catalyzed cycloaddition which favors the 1,4 substitutedproduct.
2.One step catalytic alternative to the classic Wittig reaction.
3.Ruthenium catalyzed stereospecific living radical gradient copolymerization of acrylate monomer pairs.
References : 1. J. Am. Chem. Soc.. 2005, 127, 15998 2.J. Am. Chem. Soc., 2008, 130, 8923. 3.Organometallics, 2007, 26, 302.