![Acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1H-imidazole]ruthenium(II) hexafluorophosphate, min. 98% [Alkene Zipper Catalyst],乙腈(环戊二烯基)[2(-(二-异丙基膦基)-4-(叔丁基)-1-甲基-1H-咪唑]钌(II)六氟磷酸盐 , min. 98%](https://static.jkchemical.com/Structure/142/1428988.png)
乙腈(环戊二烯基)[2(-(二-异丙基膦基)-4-(叔丁基)-1-甲基-1H-咪唑]钌(II)六氟磷酸盐 , min. 98%
Acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1H-imidazole]ruthenium(II) hexafluorophosphate, min. 98% [Alkene Zipper Catalyst]
分子式: C₂₁H₃₅F₆N₃P₂Ru
分子量: 606.53
纯度: min. 98%
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基本信息
安全信息
存储条件Store at 2-8℃ |
化学和物理性质
产品描述
Technical Note:
1."Zipper" catalyst for alkene isomerization over up to 30 double bond positions (Ref. 1). Selective isomerization over one position also possible (Ref. 2, 3). Depending on substrate structure, H/D exchange at accessible allylic positions can be accompanied by is omerization (Ref. 4).
References :
1. J Am. Chem. Soc..2007, 129, 9592. 2.Topics in Catalysis, 2010, 53, 1015. 3. J. Am. Chem. Soc.2012, 134, 10357.
