![Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II),氯(4-氰基苯基)(R)-1-[(S)-2-(双(4-氟苯基)二茂铁膦基]乙基(二叔丁基膦基)镍(II)](https://static.jkchemical.com/Structure/240/2406638.png)
氯(4-氰基苯基)(R)-1-[(S)-2-(双(4-氟苯基)二茂铁膦基]乙基(二叔丁基膦基)镍(II)
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
分子式: C??H??ClF?FeNNiP
分子量: 774.69
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1. Versatile air-stable low cost nickel catalyst alte rnative to palladium for carbon- carbon and carbon- heteroatom cross-coupling reactions .
2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines
3. Used in monoarylation experiments using comme rcially available ammonia gas, ammonium salts or ammonia stock solutions
4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hyd rochloride salts 3
References:
1.Org. Process Res. Dev., 2015, 19, 1936.
2.Angew. Chem, Int. Ed. 2015, 54, 37 73.
3.Angew. Chem, Int. Ed. 2015, 54, 3768.
