![Chloro(4-cyanophenyl){(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl(di-t-butyl)phosphine} nickel(II),氯(4-氰基苯基)(R)-1-[(S)-2-(二苯基膦基)二茂铁]乙基(二叔丁基)膦镍(II)](https://static.jkchemical.com/Structure/240/2406635.png)
氯(4-氰基苯基)(R)-1-[(S)-2-(二苯基膦基)二茂铁]乙基(二叔丁基)膦镍(II)
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl(di-t-butyl)phosphine} nickel(II)
分子式: C??H??ClFeNNiP
分子量: 738.71
纯度: null
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbon- heteroatom cross-coupling reactions .
2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines
3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions
4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts
References:
1Org.Process Res. Dev., 2015, 19, 1936.
2.Angew. Chem, Int. Ed., 2015, 54, 3773.
3.Angew. Chem, Int. Ed., 2015, 54, 3768.
