(R)-1-[(R)-α-(二甲胺基)-2-(二苯基膦)苄基]-2-二苯基膦二茂铁 , min. 97%
(R)-(+)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97%
分子式: C??H??FeNP
分子量: 687.57
纯度: min. 97%
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存储条件Store at 2-8℃ |
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Technical Notes:
1.Ligand for copper-catalyzed asymmetric allylic alkylation of halocrotonates
2.L igand for silver-catalyzed asymmetric 1 ,3-dipolar cycloadditions of a-iminonitriles
3.L igand for copper- catalyzed enantioselective reductive couplings of alkenylazaarenes with ketones
4.L igand for copper-catalyzed chiral Mannich-type reactions of y-butenolides and N-thiophosphinoyl ketimines
5.L igand for palladium catalyzed asymmetric borylation
6.L igand for copper-catalyzed enantiodivergent hydroboration of bicyclic alkenes
References : 1.Adv. Synth. Catal. 2010, 352, 999. 2.Chem. Commun.. 2011, 47, 6784. 3.J. Am. Chem. Soc.. 2012, 134, 8428. 4.Angew. Chem. Int. Ed.. 2013, 52, 7310 5.Angew. Chem. Int. Ed.. 2013, 52, 8069. 6.Org. L ett., 2015, 17, 764.