![(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%,S,S)-(+)-2,2'-Bis[?-(N,N-二甲氨基)(苯基)甲基]-1,1'-双(二环己基磷)二茂铁 , min. 97%](https://static.jkchemical.com/Structure/136/136660.png)
S,S)-(+)-2,2'-Bis[?-(N,N-二甲氨基)(苯基)甲基]-1,1'-双(二环己基磷)二茂铁 , min. 97%
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%
分子式: C??H??F??FeN?P
分子量: 1364.74
纯度: min. 97%
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Technical Notes:
1.Ligand for Rh-catalyzed asymmetric hydrogenation of a-acetamidoacrylates.
2. Ligand for Rh-catalyzed hydrogenation of a- and ß- enamides, acrylic acid derivatives, itaconates, ß-ketoesters and 1 ,3diketones.
3.Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives .
4.Ligand for lr-catalyzed asymmetric transfer hydrogenation of ketones.
5.Ligand for Cu-catalyzed e nantiosele ctive hydroboration of a- and ß-unsaturated esters and nitriles.
References: 1. Chem. Eur. J., 1998, 4, 950. 2.Tetrahedron-Asymmetr., 1999, 10, 37 5. 3.Tetrahedron-Asymmetr., 2004, 15, 2299. 4.Chem. Eur. J., 2006, 12, 5376. 5.Chem. Eur. J., 2008, 14, 1 0388. 6.Angew. Chem. Int. Ed., 2008, 47, 145.
