![(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.,(1R,2R)-(-)-[1,2-环己二胺-N,N'-双(3,5-二叔丁基水杨基)]氯化锰 , 98%](https://static.jkchemical.com/Structure/594/594498.png)
(1R,2R)-(-)-[1,2-环己二胺-N,N'-双(3,5-二叔丁基水杨基)]氯化锰 , 98%
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.
分子式: C₃₆H₅₂ClMnN₂O
分子量: 635.22
纯度: 98%
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![9-Azabicyclo[3.3.1]nonane n-oxyl,9-Azabicyclo[3.3.1]nonane n-oxyl](https://static.jkchemical.com/Structure/186/1868396.png)
基本信息
中文名称(1R,2R)-(-)-[1,2-环己二胺-N,N'-双(3,5-二叔丁基水杨基)]氯化锰 | 英文名称(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat. |
产品编号25-0300 | 分子式C₃₆H₅₂ClMnN₂O |
CAS号138124-32-0 | 分子量635.22 |
产品纯度98% | |
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
2.Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corres ponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3.As ymmetric Kinetic res olution of secondary alcohols in water.
4.Enantios elective Reformatsky reaction with ketones.
References:
1.J. Org. Chem.. 1993, 58, 6939.
2.J. Am. Chem. Soc., 1994, 116, 6937
3.Encyclopedia of Reagents for Organic Synthesis, 1995, 7, 4585.
4.Angew. Chem. Int. Ed. Eng., 2003, 42, 1042.
5.Angew. Chem. Int. Ed. Eng., 2006, 45, 2951.
