![(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me,（R）-N - （（3-甲基吡啶-2-基）甲基）-7'-二（3,5-二 - 叔丁基苯基）膦基-1,1'-螺二茚满基-7-胺 , min. 98% (>99% ee)](https://static.jkchemical.com/Structure/232/2324069.png)
（R）-N - （（3-甲基吡啶-2-基）甲基）-7'-二（3,5-二 - 叔丁基苯基）膦基-1,1'-螺二茚满基-7-胺 , min. 98% (>99% ee)
(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me
分子式: C₅₂H₆₅N₂P
分子量: 749.06
纯度: min. 98% (>99% ee)
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Technical Notes:
1.Iridium/ligand catalyst for the highly efficient, as ymmetric hydrogenation of ß- aryl and ß-ketoesters .
2.Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.
3.Iridium/ligand catalyst for the highly efficient, as ymmetric hydrogenation of ß-aryI and ß-ketoesters.
Reference:
1. Angew. Chem Int. Ed., 2011, 50, 7329.
2 Angew. Chem Int. Ed., 2012, 51, 201. 3. Org. Lett., 2012, 14, 6158.
