(S)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯 , 98% (99% ee)
(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
分子式: C??H??F??O?P
分子量: 772.5
纯度: 98% (99% ee)
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Technical Note:
1.Friedel-Crafts Alkylation: Chiral phosphoric acids were used as catalysts for the Friedel-Crafts alkylations of indolyl enones while both a ruthenium complex and chiral phosphoric acids were used as catalysts for sequential olefin cross-metathesis and Friedel-Crafts alkylations of allyloxymethyl or allylaminomethyl indoles and enones.
Reference:
1. Angew. Chem. Int. Ed., 2009, 48, 7428-7431.