![(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%,(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷-环庚[2,1-a;3,4-a']二萘-4-基)二甲胺 , min. 98%](https://static.jkchemical.com/Structure/606/606216.png)
(S)-(+)-(2,6-二甲基-3,5-二氧-4-磷-环庚[2,1-a;3,4-a']二萘-4-基)二甲胺 , min. 98%
(S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, min. 98%
分子式: C??H??NO?P
分子量: 387.41
纯度: min. 98%
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Technical Notes:
1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino
acids, enamides, and unsaturated acids .
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3.L igand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4.L igand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes .
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
References: 1.J. Am. Chem. Soc., 2000, 122, 1 1539. 2.Adv. Synth. ( atal., 2003, 345, 308. 3.Adv. Synth. Catal., 2002, 344, 1 003. 4.Chem. Comm, 1999, 741 . 5.Eur. J. Inorg. Chem., 2002, 2569. 6.J. Am. Chem. Soc., 2008, 130, 3734. 7.Ad. Synth. Catal, 2012, 354, 2433. 8.J. Org. Chem., 2013, 78, 2736.
