Technical Notes:

1.See also 46-0268

2.Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates .

3.Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolatecoupling.

4.Ligand used for the chemoselective amination of aryl c hlorides.

5.L igand used for the Pd-catalyzed borylation of aryl chlorides .

a. For the formation of trifluoroborates .

6.L igand used for the Pd-catalyzed amination of vinyl halides and triflates .

7.Ligand used for the Pd-catalyzed three-component s ynthesis of indoles .

8.Ligand used for the Pt- catalyzed regioselective hydros ilylation of functionalized terminal arylalkynes.

9.Ligand used for the Pd-catalyzed synthesis of carbazoles.

10.Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC -boranes .

11.Ligand used for the direct arylation of picoline N-oxide.

12.Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents .

13.Catalyst for a phos phine-catalyzed Heine reaction.

14.L igand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes.

15.Ligand used for the silver-c atalyzed hydrogenation of aldehydes.

16.Ligand used for the palladium-catalyzed cyanation of heterycyclic halides .