![(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS,(S)-(+)-4,12-二(二(3,5-二甲苯基)膦)-[2.2]-对环芳烷 , min. 95%](https://static.jkchemical.com/Structure/622/622116.png)
(S)-(+)-4,12-二(二(3,5-二甲苯基)膦)-[2.2]-对环芳烷 , min. 95%
(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS
分子式: C??H??P
分子量: 688.86
纯度: min. 95%
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.See 15-0426
2.Chiral ligand employed in the enantioselective hydrogenation of various ketones.
3.Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
4.Chiral ligand employed in the enantioselective 2 +2 cycloaddition of oxa bicyclic alkenes with terminal alkynes.
5.Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
References: 1.Org. L ett., 2000, 2, 4173. 2.Angew. Chem. Int. Ed., 2010, 49, 9197. 3.Org. L ett., 2010, 12, 304. 4Nature Chemistry, 2012, 4, 405.
