![(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%,(11aS)-3,7-双[3,5-双(三氟甲基)苯基]-10,11,12,13-四氢-5-羟基-5-氧化物二茚并[7,1-de:1',7'-fg][1,3,2]二氧磷杂八环 , min. 98%](https://static.jkchemical.com/Structure/208/2081535.png)
(11aS)-3,7-双[3,5-双(三氟甲基)苯基]-10,11,12,13-四氢-5-羟基-5-氧化物二茚并[7,1-de:1',7'-fg][1,3,2]二氧磷杂八环 , min. 98%
(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%
分子式: C₃₃H₁₉F₁₂O₄P
分子量: 738.46
纯度: min. 98%
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Technical Notes:
1. Org anocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with ß -ketoesters: facile and atom-
economicalaccoss tochiral tetrahvdroovridinos
2.Pd(O)- catalyzed tandem deprotection/cyclization of tetrahydro -ß carbolines on allenes: application to the synthesis of indolo2, 3-aquinolizidines .
3.Enantios elective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters, catalyzed by chiral spirocyclic phos phoric acids.
References:
1. Chem Commun., 2013, 49, 1401. 2.Org. Lett., 2014, 16, 1924.
3.Chem Commun., 2014, 50, 7538.
