(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%,(S)-(6,6′-二甲氧基联苯-2,2′-二基)二[双(3,5-二甲基苯基)膦] , min. 97%
(S)-(6,6′-二甲氧基联苯-2,2′-二基)二[双(3,5-二甲基苯基)膦] , min. 97%
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
品牌: Strem
产品编号: 15-0489
分子式: C??H??O?P
分子量: 694.84
纯度: min. 97%
包装库存价格
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基本信息

安全信息

存储条件Store at 2-8℃

化学和物理性质

产品描述

Technical Note:

1.See 15-0042.

2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acidderivatives.

3.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.

4.Enantioselective copper-catalyzed asymmetric hydrosilylation of aryl ketones

5.Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction.

6.Gold(l)-catalyzed enantioselective ring expansion of allenylcyclo propanols.

7. Conjugate addition using 2-heteroaryl titanates and zinc reagents.

References:

1.Adv. Synth. Catal., 2004, 346, 842.

2.Org. Lett, 2006, 8, 4573.

3.Org. Process Res. Devel., 2001, 5, 438.

4.J. Am. Chem. Soc., 2001, 123, 1291 5.J. Org. Chem., 2007, 72, 9253.

6.J. Am. Chem. Soc., 2009, 131, 91 78. 7.Org. Lett., 2009, 11, 4200.

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