![S-(-)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin, min. 97% (S)-SYNPHOS,(S)-(-)-[(5,6),(5',6')-双(乙烯二氧)联苯-2,2'-基]二苯基磷 , min. 97%](https://static.jkchemical.com/Structure/133/133669.png)
| 包装 | 库存 | 价格 | |
|---|---|---|---|
暂无数据 | |||
推荐产品
基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
2.A ligand used for the dynamic kinetic resolution of at,ß- unsaturated lactones via asymmetric copper catalyzed conjugate reduction.
3.Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
4.Used in asymmetric P auson-Khand reaction.
5.Used in asymmetric iminonitroso Diels-Alder re action.
6.Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines
References:
1.Tetrahedron L ett., 2003, 44, 823.
2.Angew. ( hem. Int. Ed., 2005, 44, 61 77.
3.J. Org. Chem., 2010, 75, 1 90.
4.Adv. Synth. Catal., 2007, 349, 1 999.
5.Tetrahedron L ett., 2009, 50, 5879.
6.J. Org. Chem., 2007, 72, 3729.
