2-(二叔丁基膦甲基-6-二乙氨基甲基)吡啶 , 98%
2-(Di-t-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine, 98%
分子式: C₁₉H₃₅N₂P
分子量: 322.47
纯度: 98%
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Technical Notes:
1. Ligand/Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
2. Ligand/ catalyst for the hydrogenation of esters in high yields under mild pressure and neutral
conditions.
3. Ligand/Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields
under neutral conditions.
4. Ligand/Catalytic hydrogenation of dimethyl carbonate, methyl carbamates, and methyl formate, a route to methanol based on co and CO2.
References: 1.Science, 2007, 31 7, 790. 2.Angew. Chem. Int. Ed., 2006, 45, 11 13. 3.J. Am. Chem. Soc., 2005, 127, 12429. 4.J. Am. Chem. Soc., 2005, 127, 10840. 5.Nature, Chem., 2011, 3, 609. 6.Chem. Soc., 2005, 127, 10840