(4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷 , min. 98%
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclo-pentane, min. 98% (~2:1 mixture of diastereomers)
分子式: C??H??ClNOSi
分子量: 267.83
纯度: min. 98%
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基本信息
安全信息
存储条件Store at 2-8℃ |
化学和物理性质
产品描述
Technical Notes:
1. Strained silacycles in Organic Synthesis: A new reagent for the enantioselective allylation of aldehydes .
2. Enantioselective allylation of ketone-derived benzoylhydrazones: Practical synthesis of tertiary carbinamines. 3.Phenol-directed enantioselective allylation of aldimines and ketimines.
4. Enantioselective imidazole directed allylation of aldimines and ketimines.
References:
1.J. Am. Chem. Soc., 2002, 124, 7920 2.J. Am. Chem. Soc., 2004, 126, 5686 3.Org. Lett., 2006, 8, 6119
4.Org. L ett., 2007, 9, 3699
