(4S,5S)-1,4-二甲基-2-2-氯-3-2,5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷 , min. 98%
(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
分子式: C₁₆H₁₈ClNOSi
分子量: 303.86
纯度: min. 98%
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基本信息
安全信息
存储条件Store at 2-8℃ |
化学和物理性质
产品描述
Technical Notes:
1.Reagent used in the enantioselective Friedel-Crafts alkylations with benzoylhydrazones .
2. Reagent used in highly enantioselective 3+2 acylhydrazone-enol ether cycloadditions.
References:
1. J. Am. Chem. Soc., 2005, 127, 2858.
2.J. Am. C hem. Soc., 2005, 127, 9974
3.Angew. Chem. Int. Ed., 2009, 48, 2403 .
4.J. Am. Chem. Soc., 2009, 131, 14638.
5.Org. L ett., 2012, 14, 2610.