![(S)-7,7’-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Sa,S,S)-SpiroBOX,（S)-7,7双[（4S)-（苯基)恶唑-2-基)-2,2,3,3-四氢-1，1,6,6'-二醇 , min. 97%](https://static.jkchemical.com/Structure/100/1000979.png)
（S)-7,7双[（4S)-（苯基)恶唑-2-基)-2,2,3,3-四氢-1，1,6,6'-二醇 , min. 97%
(S)-7,7’-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Sa,S,S)-SpiroBOX
分子式: C??H??N?O
分子量: 510.62
纯度: min. 97%
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1.Chiral ligands for copper- catalyzed asymmetric insertions of carbenoids into N- H bond of anilines.
2.Chiral ligands for copper or palladium-catalyzed asymmetric insertions of carbenoids into o -H bond of phenols.
3.Chiral ligands for copper or iron-catalyzed asymmetric insertions of carbenoids into o H bond of water.
4.Chiral ligands for copper-catalyzed asymmetric insertions of carbenoids into S-H bonds of arylmethylene mercaptans.
References: 1.J. Am. Chem. Soc. 2007. 129, 5834 5835 2.J.Am. Chem.Soc.2012, 134 436442. 3.J. Am. Chem. Soc. 2007. 129, 12616 -12617. 4.Angew. Chem., Int. Ed.. 2013, 52, 2555. 5.Angew. Chem., Int. Ed., 2014, 53, 2978 6.Angew. Chem. Int. Ed., 2008, 47, 932 -934. 7.Nature Chemistry, 2010, 2, 546 551. 8.Chem. Commun.. 2009, 5362.
