![3-[[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]amino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee),3-[[(1R,2R)-2-(1-哌啶基)环己基]氨基]-4-[[4-(三氟甲基)苯基]氨基]-3-环丁烯-1,2-二酮 , 98%, (99% ee)](https://static.jkchemical.com/Structure/910/9108691.png)
3-[[(1R,2R)-2-(1-哌啶基)环己基]氨基]-4-[[4-(三氟甲基)苯基]氨基]-3-环丁烯-1,2-二酮 , 98%, (99% ee)
3-[[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]amino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)
分子式: C??H??F?N?O
分子量: 421.50
纯度: 98%, (99% ee)
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Technical Notes:
1.Macheal Addition- highly enantioselective Michael addition reaction of diphenyl phosphite to a range of nitroalkenes .
2.Hydrophosphonylation- diphenylphosphite has been successfully employed in a chiral Pudovik reaction with aldehydes, extending the generality of this asymmetric methodology.
3.Friedel-Crafts/Substitution Domino Reaction- Dihydroarylfuran skeletons are efficiently synthesized from (Z)- bromonitroalkenes and naphthol derivatives in good yields and excellent enantioselectivities
References:
1.Angew. Chem. Int. Ed., 2010, 49, 153-1 56.
2.Org. Biomol. Chem., 2014, 12, 1258-1264.
3.Angew. Chem. Commun., 2013, 49, 2001-2003.
