2-[2,6-双(1-甲基乙基)苯基]-3,3-二甲基-2-氮鎓螺[4.5]癸-1-烯氢二氯 , min. 97%
2-[2,6-Bis(1-methylethyl)phenyl]-3,3-dimethyl-2-azoniaspiro[4.5]dec-1-ene hydrogen dichloride, min. 97% Cyclohexyl-CAAC
分子式: C??H??N∙HCl
分子量: 398.45
纯度: min. 97%
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Technical Notes:
1.Cyclic Alkyl Amino Carbene (CAAC) ligand for ruthenium-catalyzed ethenolysis to cleave carbon- carbon double bonds.
2.Ligand for rhodium-catalyzed hydrogenation of readily available fluorinated arenes to form to all-cis- (multi )fluorinated cyclo alkanes.
References: 1. Angew. Chem. Int. Ed., 2015, 54, 1919. 2. Science, 201 7, 357, 908.