(11bR)-2,6-双[4-(9-蒽基)-2,6-双(异丙基)苯基]-4-羟基-4-氧化物-二萘酚[2,1-d:1',2'-f][1,3,2]二氧磷,95%,(99%ee) , 95%, (99% ee)
(11bR)-2,6-Bis[4-(9-anthracenyl)-2,6-bis(isopropyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)
分子式: C??H??O?P
分子量: 1021.2
纯度: 95%, (99% ee)
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Organocatalyst for enantioselective Friedel-Crafts alkylation reaction of indoles with a,ß-unsaturated acylphosphonates.
2.Used in the L ewis base/chiral Brønsted acid catalyzed enantioselective bromocycloetherification.
3.Chiral phosphoric acid catalyst for the kinetic resolution of indolines based on a self-redox re action.
References:
1.Chem. Commun. 2010, 46, 4112. 2.Org. Lett..2012, 14, 256
3.Angew. Chem. int. Ed. 2016, 55, 3148.