![(8aR)-18-Hydroxy-8,9-diphenyl-18-oxide-diphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepin, 98%, (99% ee),(R)-VAPOL膦酸酯 , 98%, (99% ee)](https://static.jkchemical.com/Structure/789/789148.png)
(R)-VAPOL膦酸酯 , 98%, (99% ee)
(8aR)-18-Hydroxy-8,9-diphenyl-18-oxide-diphenanthro[4,3-d:3',4'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
分子式: C??H??O?P
分子量: 600.6
纯度: 98%, (99% ee)
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Technical Notes:
1.Organocatalyst for amidation of imines .
2.Organocatalyst for desymmetrization of meso- aziridines.
3.Chiral Brønsted acid used in catalytic asymmetric aza-D arzens aziridine synthesis.
4.Organocatalyst forthe remote a-C -H bond activation of alcohols or amines triggered by the radical
trifluoromethylation of alkenes .
5.Used in the enantioselective Pd/Brønsted acid-catalyzed carbonylative carbocyclization of enallenes via cross -dehydrogenative coupling with terminal alkynes.
6.Co-catalyst used in Co/achiral pyridine ligand catalyzed enantioselective radical oxytrifluoromethylation of alkenes with alcohols .
7.Used in the enantioselective synthesis of tropanes via Brønsted acid catalyzed pseudotransannular
desymmetrization.
