![[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-phenylethyl]-2-methyl-2-propanesulfinamide, 95%,[S(R)]-N-[(1S)-2-(二苯基膦基)-1-苯基乙基] -2-甲基-2-丙烷亚磺酰胺,95％ , 95%](https://static.jkchemical.com/Structure/902/9025909.png)
[S(R)]-N-[(1S)-2-(二苯基膦基)-1-苯基乙基] -2-甲基-2-丙烷亚磺酰胺,95％ , 95%
[S(R)]-N-[(1S)-2-(Diphenylphosphino)-1-phenylethyl]-2-methyl-2-propanesulfinamide, 95%
分子式: C??H??NOPS
分子量: 409.5
纯度: 95%
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Technical Notes:
1.Sulfinamide phos phine organocatalyst for the enantioselective intramolecular Rauhut-Currier reaction.
2.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1,3-dienes with vinyl ketones.
3.Used in the enantioselective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates.
4.L igand for the direct Pd-catalyzed cross-coupling reaction of easily accessible secondary phosphine oxides and aryl bromides, which provides rapid access to P-chiral phosphine oxides.
References:
1. Angew. Chem. Int. Ed. 2015, 54, 6874.
2.Org. Lett. 2017, 19, 1710.
3.Org. Lett. 2017, 19, 6080.
4.J. Am. Chem. Soc. 2019, 141, 20556.
