[S(R)]-N-[(1S)-1-[(二苯基膦基)甲基] -2-甲基丙基] -2-甲基-2-丙亚磺酰胺,95% , 95%
[S(R)]-N-[(1S)-1-[(Diphenylphosphino)methyl]-2-methylpropyl]-2-methyl-2-Propanesulfinamide, 95%
分子式: C??H??NOPS
分子量: 375.5
纯度: 95%
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Technical Notes:
1.Sulfinamide phos phine organocatalyst for the enantioselective intramolecular Rauhut-Currier reaction.
2.Used in phosphine-catalyzed asymmetric intermolecular cross-vinylogous Rauhut-Currier Reactions of vinyl Ketones with para-quinone methides.
3.Used in the enantios elective phosphine-catalyzed allylic alkylations of mix-indene with MBH carbonates.
References:
1.Angew. Chem. Int. Ed. 2015, 54, 6874.
2.ACS Catal. 2017, 7, 2805.
3.Org. Lett. 2017, 19, 6080.