[S(R)]-N-[(1S)-1- [2-(二苯基膦基)苯基] -2,2-二甲基丙基] -2-甲基-2-丙烷亚磺酰胺,95% , 95%
[S(R)]-N-[(1S)-1-[2-(Diphenylphosphino)phenyl]-2,2-dimethylpropyl]-2-methyl-2-propanesulfinamide, 95%
分子式: C??H??NOPS
分子量: 451.6
纯度: 95%
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Technical Notes:
1.Ligand used for diastereo- and enantioselective Cu(I)- catalyzed intermolecular 3 +2 cycloaddition of
azomethine ylides with ß-trifluoromethyl ß,ß-Disubstituted enones.
2.Ligand used in the Copper(I)-catalyzed asymmetric intermolecular 3+2 cycloaddition of azomethine ylides with a-Trifluoromethyl a, ß-unsaturated esters .
3.Ligand used for Ag(l)-catalyzed enantioselective 3+2 cycloaddition of azomethine ylides .
References:
1.Angew. Chem. Int. Ed. 2016, 55, 6324.
2.ACS Catal. 2017, 7, 210.
3.Org. Biomol. Chem., 2019, 17, 1395.