[S(R)]-N-[(S)-[2-(二苯基膦基)苯基] -1-萘甲基] -2-甲基-2-丙烷亚磺酰胺,95% , 95%
[S(R)]-N-[(S)-[2-(Diphenylphosphino)phenyl]-1-naphthalenylmethyl]-2-methyl-2-propanesulfinamide, 95%
分子式: C??H??NOPS
分子量: 521.7
纯度: 95%
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Technical Notes:
1.Ligand for the enantioselective Au-catalyzed 3+3 cycloaddition reaction of 2-(1-alkynyl)-alk-2-en-1 -ones with nitrones .
2.Used in enantioselective Au-catalyzed synthesis of indolyl-substituted cy clopentacfurans .
3.Ligand for the enantioselective Au-catalyzed intermolecular exo 4+3-cycloaddition to generate chiral oxa- bridged benzocycloheptanes .
References:
1.Angew. Chem. Int. Ed. 2014, 53, 4350.
2.Org. Lett. 2018, 20, 6403.
3Org. Lett. 2019, 21, 3018.