![(S)-3-(tert-Butyl)-4-(2,6-diphenoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee),(S)-3-(叔丁基)-4-(2,6-二苯氧基苯基)-2,3-二氢苯并[d][1,3]氧磷,97%(>99%ee) , 97% (>99% ee)](https://static.jkchemical.com/Structure/913/9135459.png)
(S)-3-(叔丁基)-4-(2,6-二苯氧基苯基)-2,3-二氢苯并[d][1,3]氧磷,97%(>99%ee) , 97% (>99% ee)
(S)-3-(tert-Butyl)-4-(2,6-diphenoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, 97% (>99% ee)
分子式: C??H??O?P
分子量: 454.16
纯度: 97% (>99% ee)
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基本信息
安全信息
化学和物理性质
产品描述
Technical Notes:
1.Ligand used with Nickel catalyst for asymmetric intramolecular/intermolecular reductive addition. 2.Ruthenium catalyzed asymmetric addition.
3.Palladium catalyst for asymmetric intramolecular cyclization.
References:
1.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524
2.Org. Chem. Front. 2015, 2, 1322-1325
3.J. Org. Chem. 2013, 78, 6350-6355
4.Angew. Chem., Int. Ed. 2015, 54, 3033-3037
5.Tetrahedron.2016, 72, 1782- 1 786.
