![(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%,(11bR)-N,N-二甲基-2,6-二苯基二萘并[2,1-d:1',2'-f][1,3,2]二氧杂膦-4-胺 , 98%](https://static.jkchemical.com/Structure/913/9135451.png)
(11bR)-N,N-二甲基-2,6-二苯基二萘并[2,1-d:1',2'-f][1,3,2]二氧杂膦-4-胺 , 98%
(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%
分子式: C₃₄H₂₆NO₂P
分子量: 511.50
纯度: 98%
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存储条件Store at 2-8℃ |
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Technical Notes
1.L igand for the Rh-catalyzed asymmetric intermolecular hydroacylation reaction with salicylaldehydes .
2.L igand for the enantioselective Co-catalyzed 6+2 cycloadditions of cycloheptatriene with alkynes .
3.Ligand used for the Ni-catalyzed enantio- and diastereos elective three-component coupling of 1 ,3-dienes, aldehydes, and a silylborane leading to a-chiral allylsilanes.
References:
1.Adv. Synth. Catal. 2007, 349, 11 85.
2.Adv. Synth. Catal. 2008, 350, 280.
3.Angew. Chem. Int. Ed. 2012, 51,1228.
4.Org. Biomol. Chem., 2014, 12, 2745.
